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Sulfur
from the Claus Process:
In
petroleum refining, sulfur is reacted with hydrogen to form
hydrogen sulfide. In "sour" natural gas, the sulfur
occurs as hydrogen sulfide. In either case, the hydrogen sulfide
is converted to elemental sulfur. Recovered sulfur is produced
by counter-current absorption to collect the hydrogen sulfide in
a solution. The solution is normally an alkanolamine from which
the gas is distilled, then burned to produce a flue gas
consisting of hydrogen sulfide and sulfur dioxide. This is
cooled and catalyzed in a converter to produce sulfur vapor and
water. The sulfur vapor is removed from the mixture by scrubbing
with makeup liquid sulfur.
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